67502-51-6Relevant articles and documents
Direct and straightforward transfer of C1 functionalized synthons to phosphorous electrophiles for accessinggem-P-containing methanes
Touqeer, Saad,Ielo, Laura,Miele, Margherita,Urban, Ernst,Holzer, Wolfgang,Pace, Vittorio
supporting information, p. 2425 - 2429 (2021/04/02)
The direct transfer of different α-substituted methyllithium reagents to chlorinated phosphorous electrophiles of diverse oxidation state (phosphates, phosphine oxides and phosphines) is proposed as an effective strategy to synthesize geminal P-containing
DIETHYL-1-MAGNESIUM CHLORIDE METHANEPHOSPHONATE, A NOVEL GRIGNARD REAGENT AND ITS USE IN ORGANIC SYNTHESIS
Coutrot, P.,Youssefi-Tabrizi, M.,Grison, C.
, p. 13 - 18 (2007/10/02)
Diethyl-1-magnesium chloride methanephosphonate was obtained by an exchange reaction between diethyliodo methanephosphonate and isopropylmagnesium chloride in THF at -70 deg.C.Reactions of this novel Grignard reagent with various electrophiles are described, and compared with those of the analogous lithium or copper derivatives.Diethyl-1-magnesium chloride methanephosphonate is especially reactive towards phenylselenium halides and halogens.
ULTRASONIC FORMATION AND REACTIONS OF SODIUM PHENYLSELENIDE
Ley, Steven V.,O'Neil, Ian A.,Low, Caroline M. R.
, p. 5363 - 5368 (2007/10/02)
Treatment of diphenyldiselenide with sodium metal in tetrahydrofuran under ultrasonic conditions conveniently gave a suspension of sodium phenylselenide which could be transferred by syringe or cannula and reacted with sulphonates, halides and epoxides.