110344-59-7

Basic information

• Product Name: 2-(4-hydroxyphenyl)ethyl 4-O-[(2E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]-beta-D-glucopyranoside
• CAS NO: 110344-59-7
• Molecular Formula: C₂₄H₂₈O₁₀
• Molecular Weight: 476.4731
• Mol File: 110344-59-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 718.2°C at 760 mmHg
• Flash Point: 244.1°C
• Density: 1.44g/cm³
• Vapor Pressure: 1.2E-21mmHg at 25°C
• Refractive Index: 1.644
• CAS DataBase Reference: 2-(4-hydroxyphenyl)ethyl 4-O-[(2E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]-beta-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-hydroxyphenyl)ethyl 4-O-[(2E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]-beta-D-glucopyranoside(110344-59-7)
• EPA Substance Registry System: 2-(4-hydroxyphenyl)ethyl 4-O-[(2E)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoyl]-beta-D-glucopyranoside(110344-59-7)

Safety Data

• Hazardous Substances Data: 110344-59-7(Hazardous Substances Data)

Upstream product

• 183209-56-5 2-(4-benzyloxyphenyl)ethyl β-D-glucopyranoside 
• 916458-79-2 2-(4-benzyloxyphenyl)ethyl-(2,3,4,6-tetra-O-acetyl)-β-D-glucopyranoside 
• 246872-15-1 2-[3,4-bis(tert-butyldimethylsilyloxy)phenyl]ethanol 
• 421558-09-0 2-(4-allyloxyphenyl)ethyl 2,3-di-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 421558-10-3 2-(4-allyloxyphenyl)ethyl 2,3-di-O-allyl-β-D-glucopyranoside 
• 94475-61-3 (E)-3-(3-methoxy-4-benzyloxyphenyl)acrylic acid benzyl ester 
• 74808-10-9 O-(2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl)trichloroacetimidate 
• 77795-22-3 4-benzyloxy-3-methoxycinnamic acid 
• 61439-59-6 2-(4-benzyloxyphenyl)ethanol 
• 1135-24-6 (E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid 
• 83-87-4 D-glucose pentaacetate 
• 955944-28-2 2-(4-benzyloxyphenyl)ethyl 2,3-di-O-benzyl-β-D-glucopyranoside 
• 955944-30-6 2-(4-benzyloxyphenyl)ethyl 2,3-di-O-benzyl-4-O-[(E)-4-O-benzylferuloyl]-β-D-glucopyranoside 
• 861821-39-8 2-(4-allyloxyphenyl)ethyl 2,3-di-O-allyl-4-O-[(E)-(4-O-allyl)feruloyl]-6-O-allyloxycarbonyl-β-D-glucopyranoside 

Relevant articles and documents

Short Synthesis of Phenylpropanoid Glycosides Calceolarioside A and Syringalide B

An efficient and practical three-step synthesis of phenylpropanoid glycosides calceolarioside A and syringalide B in >62% overall yield is disclosed. The key step involves the chemoselective and regio selective direct O -4 cinnamoylation of unprotected 2-phenylethyl-β- d -glucosides with cinnamic anhydrides using a chiral 4-pyrrolidinopyridine organocatalyst. This approach serves as a model for the short synthesis of phenylpropanoid glycosides acylated at O -4 without protection/deprotection steps.

Total synthesis of syringalide B, a phenylpropanoid glycoside

The first total synthesis of syringalide B, 2-(4-hydroxyphenyl)ethyl 4-O-[(E)-feruloyl]-β-D-glucopyranoside, is described. The hydroxyl groups were protected with allyloxycarbonyl (Aoc) and allyl groups, which successfully prevent the migration of the fer