110354-77-3Relevant academic research and scientific papers
Enzymatic Baeyer-Villiger oxidations of some bicycloheptan-2-ones using monooxygenases from Pseudomonas putida NCIMB 10007: enantioselective preparation of a precursor of azadirachtin
Gagnon, Rene,Grogan, Gideon,Roberts, Stanley M.,Villa, Raffaella,Willetts, Andrew J.
, p. 1505 - 1512 (2007/10/02)
Two monooxygenases MO1 (NADH dependent) and MO2 (NADPH dependent) isolated from Ps. putida NCIMB 10007 have been utilized as biocatalysts in Baeyer-Villiger oxidations.The former enzyme oxidized the racemic ketones 9, 10 and 14 into
A Study of the Regioselectivity of Oxygen Insertion in the Baeyer-Villiger Oxidation of Bicycloheptan-2-ones
Hamley, Peter,Holmes, Andrew B.,Marshall, David R.,MacKinnon, John W. M.
, p. 1793 - 1802 (2007/10/02)
Synthesis and Baeyer-Villiger oxidation of the series of bicyclic ketones 3 and 6 is described.The ratio of methine to methylene carbon migration in the oxidation was found to vary depending on the 5-endo and 7-anti substituents of the ketones.Possible re
CHEMISTRY OF INSECT ANTIFEEDANTS FROM AZADIRACHTA INDICA (PART 7): PREPARATION OF AN OPTICALLY PURE HYDROXYACETAL EPOXIDE RELATED TO AZADIRACHTIN.
Anderson, James C.,Ley, Steven V.
, p. 3437 - 3440 (2007/10/02)
Preparation of an optically pure hydroxyacetal epoxide (2) as a model compound of the potent antifeedant azadirachtin (1) is reported.
Neighboring Group Participation by Pyridine Ring. 3. Synthesis and Solvolysis of 5,8-Dihydro- and 5,6,7,8-Tetrahydro-5,8-methanoquinoline Derivatives
Tanida, Hiroshi,Irie, Tadashi
, p. 5218 - 5224 (2007/10/02)
Introduction of a propionaldehyde function into the 3-exo position of 5-exo-(benzyloxy)bicycloheptan-2-one (11) followed by construction of a pyridine ring fused with the bicycloheptane ring gave 5,8-dihydro- and 5,6,7,8-tetrahydro-5,8-metha
