110355-46-9

Upstream product

• 17574-84-4 1-methoxy-2-methylprop-1-ene 
• 1538-98-3 p-tosyldiazomethane 
• 107696-98-0 3,3-dimethyl-1-(p-tolylsulfonyl)-2-(trimethylsilyl)-cyclopropene 
• 110355-39-0 3,3-dimethyl-4-(p-tolylsulfonyl)-5-(trimethylsilyl)-3H-pyrazole 
• 107696-97-9 3,3-dimethyl-4-(p-tolylsulfonyl)-5-(trimethylsilyl)-3H-pyrazole 
• 110355-40-3 [1-Diazo-3-methyl-2-(toluene-4-sulfonyl)-but-2-enyl]-trimethyl-silane 
• 34452-56-7 trimethylsilyl p-tolylsulfonylacetylene 
• 107696-99-1 trans-2,2-dimethyl-3-(p-tolylsulfonyl)cyclopropyl methyl ether 
• 79-22-1 methyl chloroformate 

Downstream Products

• 110355-47-0 methyl 3,3-dimethyl-(p-tolylsulfonyl)succinaldehyde 

Relevant academic research and scientific papers

Chemical Reactivity and Configurational Properties of Cyclopropyl Carbanions Derived from a Silyl Sulfonyl Substituted Cyclopropane

3,3-dimethyl-1-(p-tolylsulfonyl)-2-(trimethylsilyl)cyclopropene was prepared by the 1,3-dipolar cycloaddition of 2-diazopropane with p-tolyl 2-(trimethylsilyl)ethynyl sulfone followed by photoextrusion of nitrogen from the resulting 3H-pyrazole.Treatment

SIGNIFICANCE OF THE ANOMERIC EFFECT ON THE CONFIGURATIONAL STABILITY OF CYCLOPROPYL CARBANIONS.

The effect on an electron withdrawing group adjacent to cyclopropyl carbanion has been studied.The facility with which carbanion interconversion occurs can be attributed to the existence of the anomeric effect.