110366-74-0Relevant academic research and scientific papers
Asymmetric Induction in the Addition Reactions of Chiral Sulfinylallyl Anions (Ambident Nucleophiles) with Enones (Ambident Electrophiles). Ring Closure of Enol Thioether Ketones
Hua, Duy H.,Venkataraman, S.,Coulter, M. Jo,Sinai-Zingde, Gurudas
, p. 719 - 728 (2007/10/02)
The regio- and stereochemical aspects of reactions of sulfinylallyl anions possessing chiral sulfur with various cyclic enones are reported.The 1,4-γ-adducts (Michael-type adducts) were obtained with excellent enantioselectivity in most cases (70-96percen
