1103748-54-4Relevant academic research and scientific papers
Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution
Bakewell, Clare,White, Andrew J. P.,Crimmin, Mark R.
, p. 12763 - 12766 (2016)
Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.
Stable adducts of a dimeric magnesium(I) compound
Green, Shaun P.,Jones, Cameron,Stasch, Andreas
supporting information; experimental part, p. 9079 - 9083 (2009/02/08)
(Figure Presented) A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long Mg-Mg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low-energy processes. The structures of the magnesium(I) adducts are compared with those of related magnesium(II) hydride complexes (see picture; Mg pink, N blue, O red, H green).
