1103771-74-9Relevant academic research and scientific papers
A chiral bidentate sp2-N ligand, naph-diPIM: Application to CpRu-catalyzed asymmetric dehydrative C-, N-, and O-allylation
Miyata, Kengo,Kutsuna, Hironori,Kawakami, Sho,Kitamura, Masato
, p. 4649 - 4653 (2011/06/27)
A handy new ligand: The CpRu complex (Cp=cyclopentadienyl) of a new type of chiral bisamidine ligand with a naphtho[1,2-b:7,8-b]dipyrroloimidazole (Naph-diPIM) skeleton with a Bronsted acid efficiently catalyzes dehydrative intermolecular C-allylation with high enantio- and regioselectivity. The catalytic system also gives nearly enantiomerically pure cycloalkanes and N- and O-heterocycles with a substrate/catalyst ratios of up to 10 000.
Organocatalytic approach to benzofused nitrogen-containing heterocycles: Enantioselective total synthesis of (+)-angustureine
Fustero, Santos,Moscardo, Javier,Jimenez, Diego,Perez-Carrion, Maria Dolores,Sanchez-Rosello, Maria,Del Pozo, Carlos
supporting information; experimental part, p. 9868 - 9872 (2009/10/20)
A study was conducted to demonstrate an organocatalytic approach to benzofused nitrogen-containing heterocycles. he study also demonstrated enantioselective total synthesis of (+)-angustureine. It reported the easy an d enantioselective preparation of tet
