110410-79-2

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 110410-78-1 (3R,4R,5R)-3-Benzyloxy-4-methyl-hexane-1,5-diol 
• 110410-75-8 Toluene-4-sulfonic acid (2S,3S,4R)-4-benzyloxy-6-methoxy-3-methyl-tetrahydro-pyran-2-ylmethyl ester 
• 110410-76-9 (2R,3R,4R)-4-Benzyloxy-6-methoxy-2,3-dimethyl-tetrahydro-pyran 
• 110410-77-0 (4R,5R,6R)-4-Benzyloxy-5,6-dimethyl-tetrahydro-pyran-2-ol 
• 85433-13-2 (1S,2S,3S,5R)-2-methyl-6,8-dioxabicyclo<3.2.1>octan-3-ol 
• 110104-51-3 ((2S,3S,4R)-4-Benzyloxy-6-methoxy-3-methyl-tetrahydro-pyran-2-yl)-methanol 
• 110104-50-2 (1S,2S,3R,5R)-3-Benzyloxy-2-methyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 100-39-0 benzyl bromide 

Relevant academic research and scientific papers

ENANTIOSELECTIVE SYNTHESIS OF 16-MEMBERED α,β,γ,δ-UNSATURATED DIOLIDE: A MODEL SYSTEM IN ELAIOPHYLIN

The synthesis of the entitled diolide (17) has been achieved starting from levoglucosan(1,6-anhydro-β-D-glucopyranose) (2) via the macrocyclization of the hydroxy acid (16) by reaction of mixed phosphoric anhydride procedure.