1104253-52-2Relevant academic research and scientific papers
The NCN-type pincer complex of palladium(II) with a 2,6-bis(2-pyridyl)-4-tert-butylbenzene tridentate ligand: synthesis, structure and catalytic activity in the mizoroki-heck reaction
Hirano, Yuichi,Saiki, Yuji,Taji, Hideki,Matsukawa, Shiro,Yamamoto, Yohsuke
, p. 1585 - 1592 (2008)
The reaction of 1-bromo-4-tert-butyl-2,6-diiodobenzene with 2-pyridylzinc chloride in the presence of catalytic Pd(PPh3)4 afforded an NCN-type pincer palladium(II) complex with two pyridine donors. The structure of the complex was determined by X-ray crystallography. The complex was found to catalyze the Mizoroki-Heck reaction at 250 °C under aerobic conditions.
