Heterocycles p. 1585 - 1592 (2008)
Update date:2022-09-26
Topics:
Hirano, Yuichi
Saiki, Yuji
Taji, Hideki
Matsukawa, Shiro
Yamamoto, Yohsuke
The reaction of 1-bromo-4-tert-butyl-2,6-diiodobenzene with 2-pyridylzinc chloride in the presence of catalytic Pd(PPh3)4 afforded an NCN-type pincer palladium(II) complex with two pyridine donors. The structure of the complex was determined by X-ray crystallography. The complex was found to catalyze the Mizoroki-Heck reaction at 250 °C under aerobic conditions.
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