110477-12-8

Upstream product

• 4694-02-4 4-(Buten-3-yl)-3-methyl-cyclohexen-2-on 
• 70436-07-6 6-(3-Butenyl)-3-ethoxy-2-cyclohexen-1-one 
• 120950-89-2 3-ethoxy-6-(2-tetrahydropyranyl-3-oxy-propyl)-cyclohex-en-1-one 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 120950-90-5 3-methyl-4-(3-hydroxypropyl)-cyclohex-2-en-1-one 

Downstream Products

• 120950-87-0 3-methyl-4-<3-pentenyl-5-(trimethylsilyl)>-cyclohex-2-en-1-one 

Relevant academic research and scientific papers

STEREOSELECTIVE CYCLIZATION OF ALLYLSILANES AND -STANNANES

The syntheses and additions of allylsilanes, and -stannanes to enones and dienones forming spiro- and fused-bicyclic products are described.The stereoselectivity observed is dependent on the Lewis acid used.The tin terminator reverses the stereoselectivit

INTRAMOLECULAR CYCLIZATIONS OF ALLYL- AND PROPARGYLSILANES

Allylsilanes of type 5 and propargylsilanes of type 13 undergo efficient cyclizations upon treatment with EtAlCl2 in toluene to afford stereoselectively functionalized hydrindanones of type 6 and spirodecanes of type 14.