120950-87-0

Upstream product

• 917-54-4 methyllithium 
• 121009-82-3 3-ethoxy-6-<3-pentenyl-5-(trimethylsilyl)>-cyclohex-2-en-1-one 
• 63922-69-0 (2-trimethylsilylethylidene)triphenylphosphorane 
• 110477-12-8 3-methyl-4-(3-oxo-propyl)-cyclohex-2-en-1-one 
• 13361-64-3 trimethyl(propargyl)silane 
• 112123-41-8 5-[(tetrahydropyran-2-yl)oxy]-1-(trimethylsilyl)-2-pentyne 
• 97997-89-2 (Z)-5-(trimethylsilyl)-3-penten-1-ol 
• 86486-02-4 1-(Trimethylsilyl)-2-pentyn-5-ol 
• 97997-99-4 1-<3-pentenyl-5-(trimethylsilyl)>-methanesulfonate 
• 120950-81-4 1-iodo-5-trimethylsilyl-3-pentene 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 4694-02-4 4-(Buten-3-yl)-3-methyl-cyclohexen-2-on 
• 70436-07-6 6-(3-Butenyl)-3-ethoxy-2-cyclohexen-1-one 

Relevant academic research and scientific papers

STEREOSELECTIVE CYCLIZATION OF ALLYLSILANES AND -STANNANES

The syntheses and additions of allylsilanes, and -stannanes to enones and dienones forming spiro- and fused-bicyclic products are described.The stereoselectivity observed is dependent on the Lewis acid used.The tin terminator reverses the stereoselectivit

INTRAMOLECULAR CYCLIZATIONS OF ALLYL- AND PROPARGYLSILANES

Allylsilanes of type 5 and propargylsilanes of type 13 undergo efficient cyclizations upon treatment with EtAlCl2 in toluene to afford stereoselectively functionalized hydrindanones of type 6 and spirodecanes of type 14.