110486-32-3

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 110474-25-4 (3S,4S,6S)-3,4-Dihydroxy-6-phenylsulfanyl-cyclohex-1-enecarboxylic acid methyl ester 
• 1822-73-7 phenylthioethylene 
• 99268-86-7 (+/-)-3-p-toluenesulfinyl-2-pyrone 
• 110474-24-3 (1S,4S,8S)-8-Phenylsulfanyl-4-(toluene-4-sulfinyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one 

Downstream Products

• 110474-28-7 (3S,4S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-cyclohexa-1,5-dienecarboxylic acid methyl ester 
• 110474-26-5 (3R,4R,6R)-6-Benzenesulfinyl-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-cyclohex-1-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Highly Stereocontrolled Synthesis of Some Polyfunctionalized Cyclohexenes. A Short Formal Total Synthesis of (+/-)-Chorismic Acid

Lewis acid catalysis or high pressure is an effective means for promoting stereocontrolled 2 + 4 cycloaddition between pyrone sulfoxide 1 and vinyl ethers and vinyl thioethers.The bridged, bicyclic lactone cycloadducts are versatile synthons carrying much