1822-73-7

Basic information

• Product Name: PHENYL VINYL SULFIDE
• Synonyms: Phenyl Vinyl Sulfide (stabilized with TBC);phenyl(vinyl)sulfane;(Ethenylthio)benzene;Ethenyl phenyl sulfide;Phenyl vinyl sulfide,97%;ethenylsulfanylbenzene;(Vinylsulfanyl)benzene;Benzene,(ethenylthio)-
• CAS NO: 1822-73-7
• Molecular Formula: C₈H₈S
• Molecular Weight: 136.21
• EINECS: 217-351-2
• Product Categories: Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds
• Mol File: 1822-73-7.mol
• Article Data: 87

Chemical Properties

• Boiling Point: 94-95 °C25 mm Hg(lit.)
• Flash Point: 114 °F
• Appearance: clear slightly yellowish liquid
• Density: 1.042 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.492mmHg at 25°C
• Refractive Index: n20/D 1.599(lit.)
• Storage Temp.: 2-8°C
• BRN: 969970
• CAS DataBase Reference: PHENYL VINYL SULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENYL VINYL SULFIDE(1822-73-7)
• EPA Substance Registry System: PHENYL VINYL SULFIDE(1822-73-7)

Safety Data

• Statements: 10
• Safety Statements: 16
• RIDADR: UN 1993 3/PG 3
• WGK Germany: 3
• F: 13
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 1822-73-7(Hazardous Substances Data)

Usage

Chemical Description

Phenyl vinyl sulfide and aryl nitrile oxides are starting materials for the reaction, and the isoxazoline compounds are intermediates in the synthesis of the b-enamino thioesters.

Chemical Properties

CLEAR SLIGHTLY YELLOWISH LIQUID

Uses

Phenyl vinyl sulfide was used in the synthesis of 2-fluoropyridinyl-6-oxy- precursors.

Synthesis Reference(s)

Journal of the American Chemical Society, 81, p. 2146, 1959 DOI: 10.1021/ja01518a032Synthesis, p. 577, 1978Tetrahedron Letters, 33, p. 199, 1992 DOI: 10.1016/0040-4039(92)88049-B

InChI:InChI=1/C8H8S/c1-2-9-8-6-4-3-5-7-8/h2-7H,1H2

Upstream product

• 699-12-7 2-(phenylthio)ethanol 
• 622-20-8 1,2-bis(phenylthio)ethane 
• 5535-49-9 2-Chloroethyl phenyl sulfide 
• 51207-25-1 ethylphenylsulfoxide 
• 60-29-7 diethyl ether 
• 591-51-5 phenyllithium 
• 108-98-5 thiophenol 
• 123-63-7 paracetaldehyde 
• 420-12-2 thirane 
• 1608-42-0 benzenedizolium-2-carboxylate 
• 4661-46-5 2-carboxybenzene diazonium chloride 
• 6008-80-6 2-ethyl-1,3-dithiolane 
• 50-00-0 formaldehyd 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 

Downstream Products

• 622-20-8 1,2-bis(phenylthio)ethane 
• 943-78-2 hexyl phenyl sulfide 
• 120831-70-1 1,4-diphenyl-2-phenylsulfanyl-1,2,3,4-tetrahydro-1,4-methano-triphenylen-13-one 
• 3389-44-4 (+/-)-(1,4,5,6,7,7-hexachloro-norborn-5-ene-2endo-yl)-phenyl sulfide 
• 5535-48-8 PVS 
• 17101-82-5 E-β-bromovinyl phenyl sulfide 
• 160661-43-8 1,2-dibromo-1-phenylsulfanyl-ethane 
• 101267-65-6 2-phenylsulfanyl-heptanoic acid 
• 63196-76-9 2-Phenylthiocyclopropylcarbonsaeuremethylester 
• 71724-33-9 1-phenyl-3-(phenylthio)pyrrolidine-2,5-dione 
• 126400-65-5 N-phenyl-3-(phenylsulfanyl)propionamide 
• 61193-42-8 2,5-Diphenyl-3-(phenylthio)pyrrolidin 
• 18889-01-5 1,1-Bis-phenylmercapto-aethylen 
• 15672-95-4 3,3-dimethylpropyl phenyl sulfide 

Relevant articles and documents

Highly efficient atom economical "green chemistry" synthesis of vinyl sulfides from thiols and acetylene in water

Potassium thiolates generated by treatment of thiols with aqueous KOH react with acetylene to give the corresponding vinyl sulfides in 90-95% yields.

Development of a highly efficient catalytic method for synthesis of vinyl ethers

A new method for the preparation of alkyl vinyl ethers has been developed. Thus, various types of alkyl vinyl ethers were synthesized by the reaction of alcohols with vinyl acetate under the influence of a catalytic amount of [Ir(cod)Cl]2 combined with Na2CO3 in good to excellent yields. Copyright

Synthesis and characterization of TiO2/Mg(OH)2composites for catalytic degradation of CWA surrogates

Surface catalyzed reactions can be a convenient way to deactivate toxic chemical warfare agents (CWAs) and remove them from the contaminated environment. In this study, pure titanium oxide, magnesium hydroxide, and their composites TiO2/Mg(OH2) were prepared by thermal decomposition and precipitation of the titanium peroxo-complex and/or magnesium nitrate in an aqueous solution. The as-prepared composites were examined by XRD, XPS, HRTEM, and nitrogen physisorption. Their decontamination ability was tested on CWA surrogates and determined by high-performance liquid chromatography (HPLC) and gas chromatography coupled with mass spectrometry (GC-MS). Dimethyl methyl phosphonate (DMMP) was used as a G simulant for the nerve agents sarin (GB) and soman (GD) while 2-chloroethyl ethyl sulfide (2-CEES) and 2-chloroethyl phenyl sulfide (2-CEPS) were used as surrogates of sulfur mustard (HD). The activity of the as-prepared composites was correlated with acid-base properties determined by potentiometric titrations and pyridine adsorption studied byin situDRIFTS. The mixing of Ti and Mg led to an increase of the surface area and the amount of surface -OH groups (with an increasing amount of Ti) that caused improved degradation of DMMP.

Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt-molybdenum catalysts

Nitrogen-doped carbon-supported cobalt-molybdenum bimetallic catalysts (abbreviated as Co-Mo/NC) are active for the hydrodeoxygenation of sulfoxides to sulfides under mild conditions (25-80 °C and 10 bar H2), which represents the first example of the use of heterogeneous non-noble metal catalysts for this transformation. MoO3 with Lewis acid sites assists the hydrodeoxygenation of sulfoxides into sulfides by hydrogen over cobalt nanoparticles.