110488-15-8Relevant academic research and scientific papers
Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(iii) porphyrins with triflate as a counter anion
Chen, Guo-Qiang,Xu, Zhen-Jiang,Zhou, Cong-Ying,Che, Chi-Ming
, p. 10963 - 10965 (2011)
[Fe(Por)CF3SO3] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
Formation, Characterization, and Reactivity of the Oxene Adduct of iron(III) Perchlorate in Acetonitrile. Model for the Reactive Intermediate of Cytochrome P-450
Sugimoto, Hiroshi,Tung, Hui-Chan,Sawyer, Donald T.
, p. 2465 - 2470 (2007/10/02)
Combination of iron(III) perchlorate with pentafluoroiodosobenzene, m-chloroperbenzoic acid, or ozone in acetonitrile at -35 deg C yields a green porphyrin-oxene adduct.This species, which has been characterized by spectroscopic, magnetic, and electrochemical methods, cleanly and stereospecifically epoxidizes olefins (>99percent exo-norbornene oxide).The reaction chemistry and electronic characterization of the adduct are consistent with an oxygen atom covalently bound to an iron(II)-porphyrin radical center (Por.-)FeII(O)+>.The latter has the spectral, magnetic, and redox characteristics of compound I of horseradish peroxidase (HRP) and the selective stereospecific oxygenase character of the reactive intermediate for cytochrome P-450.Reduction of the green species by one electron equivalent yields a red species, PorFeII(O), which has the spectral characteristics and reactivity of compound II of HRP.The iron(III)-porphyrin is an efficient catalyst for (a) the stereospecific epoxidation of olefins and (b) the oxidative cleavage of α-diols by F5PhIO and m-ClPhC(O)OOH; with H2O2, there is extensive attack on the porphyrin ring and no significant reaction with olefins or α-diols.
