110509-85-8Relevant academic research and scientific papers
A facile stereoselective synthesis of (2E)-3-silylallylic alcohols by hydromagnesiation of 1-aryl-2-silylacetylenes
Cai, Mingzhong,Zhou, Zhou,Jiang, Jianwen
, p. 1400 - 1402 (2006)
Hydromagnesiation of 1-aryl-2-silylacetylenes 1 in diethyl ether gave (1E)-2-silylvinyl Grignard reagents 2, which reacted with aldehydes or ketones 3 to afford stereoselectively (2E)-3-silylallylic alcohols 4 in good to high yields. Wiley-VCH Verlag GmbH
Formation and Reactions of Olefins with Vicinal Silyl and Stannyl Substituents
Mitchell, T. N.,Wickenkamp, R.,Amamria, A.,Dicke, R.,Schneider, U.
, p. 4868 - 4874 (2007/10/02)
The silicon-tin bond in Me3SiSnR3 (R=Me, n-Bu) adds regio- and stereospecifically to 1-alkynes and also to a limited number of nonterminal alkynes when Pd(PPh3)4 is added as a catalyst.The use of the (Z)-silylstannylalkenes thus formed in synthesis either
