110519-44-3Relevant academic research and scientific papers
An Efficacious C-Glucosidation of β-Ketoesters and ketones via Enamines
Allevi, Pietro,Anastasia, Mario,Ciuffreda, Pierangela,Fiecchi, Alberto,Scala, Antonio
, p. 57 - 58 (2007/10/02)
A route for the synthesis of α-C-glucosides of β-keto esters and ketones through the reaction of the corresponding enamines with 3,3,4,6,tetra-O-benzyl-α-D-glucopyranosyl chloride activated by silver(I) trifluoromethanesulphonate is described.
The First Direct Method for C-Glucopyranosyl Derivatization of 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Allevi, Pietro,Anastasia, Mario,Ciuffreda, Pierangela,Fiecchi, Alberto,Scala, Antonio
, p. 1245 - 1246 (2007/10/02)
Commercially available 2,3,4,6-tetra-O-benzyl-D-glucopyranose, activated by trifluoroacetic anhydride reacts, in the presence of Lewis acids, with various silyl enol ethers or with allylsilane to yield C-D-glucopyranosyl derivatives of the α-configuration
