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58518-76-6

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58518-76-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 58518-76-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,8,5,1 and 8 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 58518-76:
(7*5)+(6*8)+(5*5)+(4*1)+(3*8)+(2*7)+(1*6)=156
156 % 10 = 6
So 58518-76-6 is a valid CAS Registry Number.

58518-76-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(4-chlorophenyl)ethenoxy-trimethylsilane

1.2 Other means of identification

Product number -
Other names 1-(trimethylsiloxy)-1-p-chloro-phenylethene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58518-76-6 SDS

58518-76-6Relevant articles and documents

Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts

Bouquin, Maxime,Jaroschik, Florian,Taillefer, Marc

supporting information, (2021/06/11)

A ligand and base-free copper catalyzed synthetic method for the efficient α-arylation of aromatic ketones is described. In order to avoid strong bases, ketone-derived silyl enol ethers were employed. Their reaction with diaryliodonium salts as aryl source provided the intermolecular C–C coupling displaying good functional group tolerance and requiring low catalyst loading.

Lewis Acid-Catalyzed Carbofunctionalization of Uncommon C, N-Diacyliminium Ions: Controlling Regio- And Enantioselectivity

Brasholz, Malte,Bresien, Jonas,Frahm, Mario,Gronbach, Lisa Marie,Michalik, Dirk,Villinger, Alexander,Voss, Alice

supporting information, p. 7834 - 7838 (2021/10/20)

The tricyclic azepino[1,2-a]indole acetates 7, readily accessible by visible-light-driven catalytic photooxygenation of cyclohepta[b]indoles 1, are convenient precursors to novel and uncommon cyclic C,N-diacyliminium ions 3. We report here the first Lewis

The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp3)-O Arylation

Mills, L. Reginald,Monteith, John J.,Dos Passos Gomes, Gabriel,Aspuru-Guzik, Alán,Rousseaux, Sophie A. L.

supporting information, p. 13246 - 13254 (2020/09/01)

The ability to understand and predict reactivity is essential for the development of new reactions. In the context of Ni-catalyzed C(sp3)-O functionalization, we have developed a unique strategy employing activated cyclopropanols to aid the design and optimization of a redox-active leaving group for C(sp3)-O arylation. In this chemistry, the cyclopropane ring acts as a reporter of leaving-group reactivity, since the ring-opened product is obtained under polar (2e) conditions, and the ring-closed product is obtained under radical (1e) conditions. Mechanistic studies demonstrate that the optimal leaving group is redox-active and are consistent with a Ni(I)/Ni(III) catalytic cycle. The optimized reaction conditions are also used to synthesize a number of arylcyclopropanes, which are valuable pharmaceutical motifs.

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