110522-43-5Relevant academic research and scientific papers
Stereoselective syntheses of β-D-ribonucleosides catalyzed by the combined use of silver salts and diphenyltin sulfide or Lawesson's reagent
Shimomura,Matsutani,Mukaiyama
, p. 3100 - 3106 (1994)
β-D-Ribonucleosides are stereoselectively synthesized in high yields from methyl 2,3,5-tri-O-benzoyl-β-D-ribofuranosyl carbonate and trimethylsilylated nucleoside bases by the use of [diphenyltin sulfide/silver salt] or [Lawesson's reagent/silver salt] combined catalyst system under mild conditions.
THE STEREOCONTROLLED SYNTHESIS OF 1,2-CIS FURANOSYL NUCLEOSIDES VIA A NOVEL ANOMERIC ACTIVATION
Hanessian, Stephen,Conde, Jose J.,Lou, Boliang
, p. 5865 - 5868 (2007/10/02)
The coupling of 2-(2',3',5'-tri-O-benzyl-D-ribofuranosyloxy)-3-methoxypyridine as well as 2-(2',3',5'-tri-O-benzyl-D-ribofuranosyl)-thiopyridylcarbonate, with silylated pyrimidine bases by activation with trimethylsilyl trifluoromethanesulfonate and silve
Stereoselective synthesis of nucleosides by metallocene-promoted activation of glycosyl fluorides
Matheu Ma.,Echarri,Castillon
, p. 1093 - 1096 (2007/10/02)
The Cp2MCl2-AgX (M=Hf, Zr; X = ClO4, OTf) mixture is very effective for the promotion of the coupling of glycosyl fluorides and bis(trimethylsilyl)uracil. The stereoselectivity of the reaction depends on the solvent employ
Condensation of 1-Fluorofuranones and Silylated Nucleobases Catalyzed by Tetrafluorosilane
Noyori, Ryoji,Hayashi, Masahiko
, p. 57 - 60 (2007/10/02)
The title reaction provides a generally useful tool for nucleoside synthesis.The stereoselectivities are highly influenced by the fluoride substrates, and steric course of the reaction of O-benzylated ribofuranosyl fluoride is solvent dependent.
