86883-42-3

Upstream product

• 58381-23-0 (3R,4R,5R)-3,4-bis(benzyloxy)-5-((benzyloxy)methyl)tetrahydrofuran-2-yl acetate 
• 89361-52-4 2,3,5-tris-O-(phenylmethyl)-β-D-ribofuranose 
• 96192-07-3 2,3,5-tri-O-benzyl-L-arabinofuranose 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 86883-41-2 2,3,5-tri-O-benzyl-α-D-ribofuranosyl fluoride 

Downstream Products

• 86883-48-9 methyl 6-O-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 86883-47-8 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,5-tri-O-benzyl-α-D-ribofuranosyl)-α-D-glucopyranoside 
• 86883-50-3 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)-α-D-glucopyranoside 
• 86883-49-0 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,5-tri-O-benzyl-α-D-ribofuranosyl)-α-D-glucopyranoside 
• 90524-75-7 1-(2',3',5'-tri-O-benzyl-β-D-ribofuranosyl)propan-2-one 
• 90524-74-6 1-(2',3',5'-tri-O-benzyl-α-D-ribofuranosyl)propan-2-one 
• 98815-79-3 (2R,3R,3aS,9bR)-3-benzyloxy-2-benzyloxymethyl-3,3a,5,9b-tetrahydro-2H-furo<3,2-c><2>benzopyran 
• 88222-67-7 2-(2,3,5-Tri-O-benzyl-α,β-D-ribofuranosyl)-3-pentanon 
• 86883-44-5 3-β-cholestanyl 2,3,5-tri-O-benzyl-β-D-ribofuranoside 
• 86883-43-4 3-β-cholestanyl 2,3,5-tri-O-benzyl-α-D-ribofuranoside 
• 91110-23-5 2,3,5,2',3',5'-hexa-O-Benzyl-(β-D-ribofuranosyl β-D-ribofuranoside) 
• 110522-44-6 1-((2S,3R,4R,5R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-5-fluoro-1H-pyrimidine-2,4-dione 
• 110522-45-7 1-((2R,3R,4R,5R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl)-5-fluoro-1H-pyrimidine-2,4-dione 
• 93836-22-7 4,7-anhydro-5,6,8-tri-O-benzyl-1,2,3-trideoxy-D-altro-oct-1-enitol 

Relevant academic research and scientific papers

Synthesis of glyceryl glycosides related to A-type prymnesin toxins

A suite of glycosylated glycerol derivatives representing various fragments of the glycosylated ichthyotoxins called prymnesins were chemically synthesised. Glycerol was used to represent a small fragment of the prymnesin backbone, and was glycosylated at

Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.

A CONVENIENT, ONE-STEP, HIGH-YIELD REPLACEMENT OF AN ANOMERIC HYDROXYL GROUP BY A FLUORINE ATOM USING DAST. PREPARATION OF GLYCOSYL FLUORIDES.

The anomeric hydroxyl group of various furanose and pyranose hemiacetals can be replaced by a fluorine atom stereoselectively, conveniently, mildly, and on gram-scale using DAST in THF at room temperature.

SIMPLE SYNTHESIS OF GLYCOSYL FLUORIDES

Treatment of 1-unprotected or -O-acetylated sugar derivatives with a hydrogen fluoride-pyridine mixture affords the corresponding 1-fluoro derivatives in high yields.

STEREOSELECTIVE SYNTHESIS OF 1,2-CIS-GLYCOFURANOSIDES USING GLYCOFURANOSYL FLUORIDES

1,2-cis-Ribofuranosides are stereoselectively synthesized in high yields by the reaction of β-ribofuranosyl fluoride and alkohols in the presence of stannous chloride and trityl perchlorate.Under similar condition, α-arabinofuranosyl fluoride reacts with