110528-34-2

Upstream product

• 110528-32-0 Benzoic acid (3S,3aS,6aS,7aR)-2,2-dimethyl-2,3,3a,5,6,6a,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester 
• 98-88-4 benzoyl chloride 
• 98360-86-2 (3α,3aα,6aβ,7aα)-2,3,3a,5,6,6a,7,7a-octahydro-3-hydroxy-2,2-dimethyl-1H-cyclopentapentalene 
• 98330-87-1 6-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranyl>fulvene 
• 98330-91-7 2,3-diaza-7-<2-hydroxy-3,3-dimethylhex-5-enylidene>bicyclo<2.2.1>hept-2-ene 
• 98330-90-6 2,3-diaza-7-<5-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>hept-2-ene 
• 98330-89-3 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5'-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 110528-21-7 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 110528-18-2 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>hept-5-ene 
• 98330-88-2 N,N'-bis<(2,2,2-trichloroethoxy)carbonyl>-2,3-diaza-7-<5'-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 335383-93-2 N,N'-bis<(2,2,2-trichloroethoxy)carbonyl>-2,3-diaza-7-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 110528-19-3 7-(5-Methoxy-3,3-dimethyl-tetrahydro-furan-2-ylmethylene)-2,3-diaza-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid bis-(2,2,2-trichloro-ethyl) ester 

Relevant academic research and scientific papers

Intramolecular 1,3-Diyl Trapping Reactions. Total Synthesis of (+/-)-Hypnophilin and (+/-)-Coriolin. Formation of the Trans-Fused Bicyclooctane Ring System

The intramolecular 1,3-diyl trapping reaction served as the key step in total synthesis of (+/-)-coriolin (1) and the first total synthesis of (+/-)-hypnophilin (3).In the process, four of the required eight (coriolin) or six (hypnophilin) stereocenters w