110547-61-0Relevant articles and documents
NOVEL Si-C BOND CLEAVAGES OF ALKYLIDINESILIRANES IN THE REACTION WITH NUCLEOPHILES
Saso, Haruo,Ando, Wataru,Ueno, Katsuhiko
, p. 1929 - 1940 (1989)
1,1-Dimesityl-2-Z-neopentylidenesilirane (1Z) reacted with nucleophiles to give ring opening adducts inserting at unexpected Si-C2 bond.This behavior can be explained by the unique stuctural feature of 1Z defined by its X-ray crystal analysis.A six electr
REACTION OF SILYLENE WITH ALLENES: ALKYLIDENESILACYCLOPROPANE AND SILATRIMETHILENEMETANE
Ando, Wataru,Saso, Haruo
, p. 5625 - 5628 (2007/10/02)
Reaction of photogenerated dimethylsilylene with tert-butyldimethylallene and tert-butylallene yielded the corresponding alkylidenesilacyclopropanes.Its photochemical behavior and some reactions with nucleophiles are described.