110610-46-3Relevant academic research and scientific papers
Sterically Hindered Metal Alkenyls. Part 1. Synthesis, Reactions, and Crystal and Molecular Structures of some Palladium and Platinum ?-Alkenyls
Cardin, Christine J.,Cardin, David J.,Parge, Hans E.,Sullivan, Alice C.
, p. 2315 - 2320 (1986)
The compounds trans-C(C10H15)=CH2(PEt3)2> (1) (C10H15 = adamant-1-yl), trans C(C10H7)=CMe2(PEt3)2> , and trans-C(Ph)=CMe2(PEt3)2> have been prepared from Grignard or lithium reagents and appropiate dichlorobis(phosphine)metal derivatives.Full single-crystal X-ray data are reported for (1) and (3), and reveal unusually long Pt-C(sp2) bonds.Insertion reactions into these M-C bonds occur with MeNC , and with CO ; the latter, the first reported insertion into a Pt-C(sp2) bond, occurs under mild conditions as expected for the abnormally long M-C bonds.
