Sterically Hindered Metal Alkenyls. Part 1. Synthesis, Reactions, and Crystal and Molecular Structures of some Palladium and Platinum ?-Alkenyls

DOI: 10.1039/DT9860002315

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2315 - 2320 (1986)

Update date:2022-07-30

Topics:

Authors:

Cardin, Christine J.

Cardin, David J.

Parge, Hans E.

Sullivan, Alice C.

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Article abstract of DOI:10.1039/DT9860002315

The compounds trans-C(C10H15)=CH2<*>(PEt3)2> (1) (C10H15 = adamant-1-yl), trans C(C10H7)=CMe2<*>(PEt3)2> , and trans-C(Ph)=CMe2<*>(PEt3)2> have been prepared from Grignard or lithium reagents and appropiate dichlorobis(phosphine)metal derivatives.Full single-crystal X-ray data are reported for (1) and (3), and reveal unusually long Pt-C(sp²) bonds.Insertion reactions into these M-C bonds occur with MeNC , and with CO ; the latter, the first reported insertion into a Pt-C(sp²) bond, occurs under mild conditions as expected for the abnormally long M-C bonds.

Full text of DOI:10.1039/DT9860002315

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