Sterically Hindered Metal Alkenyls. Part 1. Synthesis, Reactions, and Crystal and Molecular Structures of some Palladium and Platinum ?-Alkenyls

DOI: 10.1039/DT9860002315

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2315 - 2320 (1986)

Update date:2022-07-30

Topics:

Authors:

Cardin, Christine J.

Cardin, David J.

Parge, Hans E.

Sullivan, Alice C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9860002315

The compounds trans-C(C10H15)=CH2<*>(PEt3)2> (1) (C10H15 = adamant-1-yl), trans C(C10H7)=CMe2<*>(PEt3)2> , and trans-C(Ph)=CMe2<*>(PEt3)2> have been prepared from Grignard or lithium reagents and appropiate dichlorobis(phosphine)metal derivatives.Full single-crystal X-ray data are reported for (1) and (3), and reveal unusually long Pt-C(sp²) bonds.Insertion reactions into these M-C bonds occur with MeNC , and with CO ; the latter, the first reported insertion into a Pt-C(sp²) bond, occurs under mild conditions as expected for the abnormally long M-C bonds.

Full text of DOI:10.1039/DT9860002315

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans-bromo[3,3-dimethyl-1-N-methylimino-2-phenylprop-2-enyl]bis(triethylphosphine)platinum(II)

Cas No:110610-46-3

R&D Labs maybe for 110610-46-3

Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China

Relevant to this article

RADICAL DECARBOXYLATIVE PHOSPHORYLATION OF CARBOXYLIC ACIDS

Doi:10.1016/S0040-4039(00)94261-8
(1986)
Synthesis of 5,6-dimethoxyquinazolin-2(1H)-ones

Doi:10.1002/jhet.5570230643
(1986)
Synthetic approaches to the microtubule-Sabilizing sponge alkaloid ceratamine A and desbromo analogues

Doi:10.1021/jo802322s
(2009)
Synthesis of a 4′,4′-spirothietane-2′, N³-cycloadenosine as a highly constrained analogue of 5′-deoxy-5′-methylthioadenosine (MTA)

Doi:10.1016/j.tetlet.2008.11.039
(2009)
A facile procedure for the synthesis of N-formyl amino acid esters

Doi:10.1055/s-1994-25628
(1994)
Synthesis of 2,3,4-trisubstituted thiochromanes using an organocatalytic enantioselective tandem michael-henry reaction

Doi:10.1002/adsc.200700331
(2008)

Article Doi