110652-88-5Relevant academic research and scientific papers
Regioselective synthesis of 1,2- and 1,3-diols from ω-hydroxy allyl acetates and carbonates via Pd complexes using boric acid and trialkyl borates
Cluzeau, Jér?me,Capdevielle, Patrice,Cossy, Janine
, p. 6945 - 6948 (2007/10/03)
The synthesis of 1,2- and 1,3-diols and derivatives has been achieved from ω-hydroxy π-allyl palladium complexes by using boric acid and trialkyl borates.
STEREOSELECTIVE SYNTHESIS OF FUNCTIONALIZED ERYTHRO/1,3-DIOLS
Mohr, Peter,Tamm, Christoph
, p. 391 - 394 (2007/10/02)
V(5+)-Catalyzed t-butylhydroperoxide epoxidation of (Z)-5-hydroxy-2-alkenylsilanes 4 exhibit good to excellent erythro selectivity.The resulting epoxides undergo fragmentation to afford 1,3-diols 8, albeit in low chemical yield.
