1108179-41-4

Basic information

• Product Name: 5-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-(2R)-(trifluoroacetyl)amino-4-(Z)-pentenoic acid tert-butyl ester
• CAS NO: 1108179-41-4
• Molecular Weight: 515.527
• Mol File: 1108179-41-4.mol

Chemical Properties

• CAS DataBase Reference: 5-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-(2R)-(trifluoroacetyl)amino-4-(Z)-pentenoic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 5-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-(2R)-(trifluoroacetyl)amino-4-(Z)-pentenoic acid tert-butyl ester(1108179-41-4)
• EPA Substance Registry System: 5-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-(2R)-(trifluoroacetyl)amino-4-(Z)-pentenoic acid tert-butyl ester(1108179-41-4)

Safety Data

• Hazardous Substances Data: 1108179-41-4(Hazardous Substances Data)

Upstream product

• 1108179-33-4 (Z)-3-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-allyl diethyl phosphate 
• 63959-88-6 tert-butyl N-(trifluoroacetyl)glycinate 

Relevant articles and documents

A straightforward approach towards glycoamino acids and glycopeptides via Pd-catalysed allylic alkylation

Chelated enolates are versatile nucleophiles for palladium-catalysed allylic alkylations. Even with complex allylic substrates the reaction proceed without significant isomerisation. This allows the stereoselective introduction of polyhydroxylated allylic sidechains into amino acids and peptides with retention of the olefin geometry.