110852-37-4Relevant academic research and scientific papers
Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds
Zhao, Yi,Jiang, Xiaojian,Yeung, Ying-Yeung
supporting information, p. 8597 - 8601 (2013/09/12)
Overriding preferences: An amine-thiocarbamate catalyst can mediate the facile, efficient, and highly enantioselective bromocyclization of olefinic 1,3-dicarbonyl compounds. In the presence of the bifunctional catalyst, the bromination occurs chemoselectively at the olefinic moiety rather than at the carbon atom in the α-position to the carbonyl units. Copyright
Synthesis and Chiroptical Properties of γ-Substituted Rigid and Conformationally Flexible Systems Having 1,3-Diene and α,β-Unsaturated Carbonyl Chromophores. The Planar Diene Rule
Walborsky, H. M.,Gawronska, K.,Gawronski, J. K.
, p. 6719 - 6726 (2007/10/02)
The syntheses of chiral (aS)-(5-hydroxyadamantylidene)- and (aS)-(5-methyladamantylidene)acetaldehyde and the corresponding adamantylidenepropene (rigid system) as well as (aS)-(4-hydroxycyclohexylidene)acetaldehyde and (aS)-(4-hydroxycyclohexylidene)prop
