110890-31-8

Basic information

• Product Name: (E)-(1R,2S)-1-Cyclohexyl-4-propylsulfanyl-2-triphenylsilanyl-but-3-en-1-ol
• CAS NO: 110890-31-8
• Molecular Weight: 486.794
• Mol File: 110890-31-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(1R,2S)-1-Cyclohexyl-4-propylsulfanyl-2-triphenylsilanyl-but-3-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(1R,2S)-1-Cyclohexyl-4-propylsulfanyl-2-triphenylsilanyl-but-3-en-1-ol(110890-31-8)
• EPA Substance Registry System: (E)-(1R,2S)-1-Cyclohexyl-4-propylsulfanyl-2-triphenylsilanyl-but-3-en-1-ol(110890-31-8)

Safety Data

• Hazardous Substances Data: 110890-31-8(Hazardous Substances Data)

Upstream product

• 76-86-8 Triphenylsilyl chloride 
• 27817-67-0 allyl-n-propyl suldide 
• 110890-28-3 1-n propylthio-3-triphenylsilyl-1-propene 
• 2043-61-0 cyclohexanecarbaldehyde 

Downstream Products

• 95061-36-2 ((1Z,3E)-4-Propylsulfanyl-buta-1,3-dienyl)-cyclohexane 

Relevant articles and documents

Stereoselective Synthesis of 1,4-Disubstituted 1,3-Diene from Aldehyde Using Organotitanium Reagent

Organotitanium reagent generated from 1-t-butylthio-3-trimethylsilyl-1-propene condenses with aldehydes to give 1-t-butylthio-(E,Z)-1,3-alkadienes in a single step via (E)-erythro-β-hydroxysilane in a highly regio- and stereoselective manner. 1,4-Dialkyl-1,3-diene is obtained from the diene sulfide by crosscoupling reaction with Grignard reagent in the presence of nickel catalyst.The utility of the method is illustrated by application to the synthesis of Spilanthol, a naturally occurring insecticide from Spilanthese olerancae in five steps.