110890-37-4Relevant academic research and scientific papers
Stereospecific Dehydrative Alkylation of Bis-Sulfones: Synthesis of a Lesser Tea Tortrix Pheromone
Yu, Jurong,Cho, Hyun-Sung,Falck, J. R.
, p. 5892 - 5894 (2007/10/02)
The intra- and intermolecular condensation of alcohols with bis-sulfone methylenes, i.e., dehydrative alkylation, using DEAD and Ph3P proceeds stereospecifically at room temperature under essentially neutral conditions affording good to excellent yields o
EFFECIENT 4 + 1 SYNTHESES OF HIGHLY FUNCTIONALIZED CYCLOPENTENES
Nantz, M. H.,Radisson, X.,Fuchs, P. L.
, p. 55 - 70 (2007/10/02)
Condensation of sulfone-activated methylene compounds with cis-1,4-dichloro-2-butene yields cyclopentenes.Elaboration of these cyclopentene products into highly functionalized intermediates is described.
