110897-22-8Relevant academic research and scientific papers
Metal-Catalyzed Remote Functionalization of ω-Ene Unsaturated Ethers: Towards Functionalized Vinyl Species
Ho, Guo-Ming,Judkele, Lina,Bruffaerts, Jeffrey,Marek, Ilan
supporting information, p. 8012 - 8016 (2018/06/29)
The combined ruthenium-catalyzed chain walking with the nickel-catalyzed cross-coupling reaction of ω-alkenyl ethers provide a unique entry to functionalized vinyl species. This transformation illustrates the power and flexibility of remote functionalization by demonstrating the compatibility of two independent reactions involving unrelated sites.
STEREO- AND REGIOSPECIFIC SYNTHESES TO PROVIDE CONJUGATED (E, Z)- AND (Z,Z)-ALKANIDES, AND ARYLATED (Z)-ALKENES IN EXCELLENT YIELDS VIA THE PALLADIUM-CATALYZED CROSS COUPLING REACTIONS OF (Z)-1-ALKENYLBORONATES WITH 1-BROMOALKENES AND ARYL IODIDES
Miyaura, Norio,Satoh, Makoto,Suzuki, Akira
, p. 3745 - 3748 (2007/10/02)
Titled alkadienes are obtained in excellent yields stereo- and regiospecifically by cross-coupling between (Z)-1-alkenylboronates and (E)- or (Z)-1-bromoalkenes in the presence of a catalytic amount of Pd(PPh3)4 and sodium ethoxide.
