110901-20-7

Basic information

• Product Name: (R)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene
• Synonyms: (R)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene
• CAS NO: 110901-20-7
• Molecular Weight: 266.458
• Mol File: 110901-20-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene(110901-20-7)
• EPA Substance Registry System: (R)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene(110901-20-7)

Safety Data

• Hazardous Substances Data: 110901-20-7(Hazardous Substances Data)

Upstream product

• 18666-34-7 1-chloro-2,2-dimethyl-1,1,2-triphenyl-disilane 
• 175982-54-4 C₃₀H₃₂OSi₂ 

Relevant articles and documents

New Synthesis of (E)-Allylsilanes with High Enantiopurity via Diastereoselective Intramolecular Bis-Silylation of Chiral Allylic Alcohols

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Synthesis of highly enantio-enriched allylsilanes via palladium-catalyzed intramolecular bis-silylation. Determination of the enantiomeric excesses through regio- and stereoselective hydroboration with 9-BBN

Highly enantio-enriched (E)-allylsilanes, were synthesized by palladium-catalyzed intramolecular bis-silylation of chiral allyl alcohols and subsequent Peterson-type elimination with organolithium reagents, The enantiomeric excesses of the allylsilanes were determined after hydroboration with 9-BBN followed by oxidation, revealing remarkably high stereospecificity for the present synthesis.