110945-45-4Relevant academic research and scientific papers
SYNTHESIS OF THE FRAGMENT GlcNAc-α(1-P-6)-GlNAc OF THE CELL WALL POLYMER OF STAPHYLOCOCCUS LACTIS HAVING REPEATING N-ACETYL-D-GLUCOSAMINE PHOSPHATE UNITS
Westerduin, P.,Veeneman, G. H.,Marel, G. A. van der,Boom, J. H. van
, p. 6271 - 6274 (2007/10/02)
The monofunctional phosphitylating reagents chloro-β-cyanoethyl-N,N-diisopropylamino-phosphoramidite (3) and salicylchlorophosphite (4) have been applied towards the introduction of an α-(1-6) interglycosidic phosphodiester bond between two properly-protected N-acetyl-D-glucosamine units.Evidence will be presented to show that 4 gives a higher yield of the requirede dimer than 3.
