111002-90-5

Upstream product

• 100-39-0 benzyl bromide 
• 76739-66-7 3,4-di-O-acetyl-D-rhamnal 
• 78086-61-0 (2R,3S,4R)-2-Methyl-3,4-dihydro-2H-pyran-3,4-diol 
• 148553-47-3 1,5-anhydro-3-O-tert-butyldiphenylsilyl-2,6-dideoxy-D-arabino-hex-1-enitol 

Downstream Products

• 110906-65-5 (2R,3R,4R,6S)-4-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-ol 
• 1403609-08-4 (2R,3R)-3-(benzyloxy)-2-methyl-2,3-dihydro-4H-pyran-4-one 
• 1161782-29-1 1,3-di-O-acetyl-4-O-benzyl-2,6-dideoxy-α-D-mannopyranose 
• 1312081-95-0 (2R,3R,4R)-3,4-bis(benzyloxy)-2-methyl-5-nitro-3,4-dihydro-2H-pyran 
• 1187458-62-3 C₃₀H₂₈O₃ 
• 1187458-61-2 C₂₇H₂₈O₄ 
• 1187458-59-8 C₂₆H₂₆O₃ 
• 132040-95-0 C₂₇H₃₀O₈S 

Relevant academic research and scientific papers

Palladium-Catalyzed One-Pot Stereospecific Synthesis of 2-Deoxy Aryl C-Glycosides from Glycals and Anilines in the Presence of tert-Butyl Nitrite

The palladium-catalyzed one-pot synthesis of 2,3-deoxy-3-keto aryl C-glycosides is achieved from glycals and anilines in the presence of tert-butyl nitrite and aqueous HBF 4 under mild conditions. This one-pot method stereospecifically provides α-and β-Aryl glycosides (≥19:1 by NMR) in good yields at room temperature. The configuration at the C-3 position in the glycal determines the anomeric selectivity (i.e., α or β) of the desired products.

Preparation method of 1,3-di-0-acetyl-4-0-benzyl-2,6-dideoxy-alpha-D-glucoside

The invention discloses a preparation method of 1,3-di-0-acetyl-4-0-benzyl-2,6-dideoxy-alpha-D-glucoside. The preparation method is characterized by adopting a two-step synthesis technology, firstly compounding 3,4-di-0-benzyl-6-deoxy-D-glucose ene by tak

Preparation method for 1-O-acetyl-3,4-di-O-benzyl-2,6-dideoxy-alpha-D-glucoside

The invention discloses a preparation method for 1-O-acetyl-3,4-di-O-benzyl-2, 6-dideoxy-alpha-D-glucoside. The preparation method is characterized by adopting a two-step method to synthesize 1-O-acetyl-3,4-di-O-benzyl-2,6-dideoxy-alpha-D-glucoside. The t

Synthesis of the C'D' disaccharide of aureolic acid

Arylbis(arylthio)sulfonium salts have been used to activate glycals towards nucleophilic addition to form principally 2-deoxy-β-glycosides. This method was applied to the synthesis of the 2-(methylphenylthio)-2'-phenylthio derivative (22) of methyl O-(4-O

Enantioselective total synthesis of medermycin (lactoquinomycin)

Medermycin has been first synthesized from D-rhamnose derivatives and comfirmed to be identical with lactoquinomycin.

SYNTHESIS OF THE DISACCHARIDE C-D FRAGMENT FOUND IN EVERNINOMICIN-C AND -D, AVALAMYCIN-A AND -C, AND CURAMYCIN-A: STEREOCHEMISTRY AT THE SPIRO-ORTHOLACTONE CENTER

The two isomers at the spiro-ortholactone center of the disaccharide C-D fragment of orthosomycins have been synthesized.Their mild acidic hydrolysis was under stereoelectronic control with each isomer leading to only one ester.It is therefore possible, f