111042-67-2

Basic information

• Product Name: ethyl 5-hydroxy-3-methyl-5-phenyl-2-pentenoate
• Synonyms: ethyl 5-hydroxy-3-methyl-5-phenyl-2-pentenoate
• CAS NO: 111042-67-2
• Molecular Weight: 234.295
• Mol File: 111042-67-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl 5-hydroxy-3-methyl-5-phenyl-2-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5-hydroxy-3-methyl-5-phenyl-2-pentenoate(111042-67-2)
• EPA Substance Registry System: ethyl 5-hydroxy-3-methyl-5-phenyl-2-pentenoate(111042-67-2)

Safety Data

• Hazardous Substances Data: 111042-67-2(Hazardous Substances Data)

Upstream product

• 111042-64-9 3-methyl(tri-n-butyltin)crotonate 
• 100-52-7 benzaldehyde 
• 92511-62-1 ethyl 3-methyl-4-(tributylstannyl)-2-butenoate 
• 111042-66-1 ethyl 3-methyl-4-(trichlorostannyl)-2-butenoate 
• 120982-20-9 ethyl 3-methyl-2-(trimethylgermyl)-3-butenoate 

Relevant articles and documents

Stabilization and activation of dienolates with germanium and tin. Stero- and regioselective aldol reactions, regioselective coupling reactions, and regioselective synthesis of amino acid derivatives

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Carbon-Carbon Bond Formation at the γ-Position of Dienolates via the Germanium Masked Dienolates

Trapping of the lithium dienolate (1), derived from 3-methyl-2-butenoate, with Me3GeX (X = Br or Cl gives the α-germylated derivative (2), which reacts with various electrophiles at the γ-position.