111063-65-1

Basic information

• Product Name: methyl 2-[(4-ethoxy-4-oxobutyl)(methyl)amino]benzoate
• Synonyms: methyl 2-[(4-ethoxy-4-oxobutyl)(methyl)amino]benzoate
• CAS NO: 111063-65-1
• Molecular Weight: 279.336
• Mol File: 111063-65-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-[(4-ethoxy-4-oxobutyl)(methyl)amino]benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-[(4-ethoxy-4-oxobutyl)(methyl)amino]benzoate(111063-65-1)
• EPA Substance Registry System: methyl 2-[(4-ethoxy-4-oxobutyl)(methyl)amino]benzoate(111063-65-1)

Safety Data

• Hazardous Substances Data: 111063-65-1(Hazardous Substances Data)

Upstream product

• 27126-43-8 N-(3-ethoxycarbonyl-propyl)-anthranilic acid methyl ester 
• 74-88-4 methyl iodide 
• 2969-81-5 Ethyl 4-bromobutyrate 
• 10072-05-6 methyl 2-(dimethylamino)benzoate 
• 140-88-5 ethyl acrylate 

Relevant articles and documents

Alkylation of the α-amino C-H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies

The Cu(ii) complex1incorporating a BP chromophore is a highly active and chemoselective photocatalyst for the alkylation of α-amino C-H bonds of anilines. The reaction was shown to proceed with a broad substrate scope in the absence of additives. Extensive mechanistic studies were performed, in particular using transient absorption spectroscopy, and spectroscopic signatures of key intermediates were identified in the conditions of catalysis. Finally, the ability of1to act as a multitask catalyst was showcased by conducting multi-component CuAAC and olefin hydroalkylation reactions in one-pot.