Cas 111112-50-6,methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate

111112-50-6

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Basic information

Product Name: methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate
Synonyms: methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate
CAS NO:111112-50-6
Molecular Formula:
Molecular Weight: 208.257
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate(CAS DataBase Reference)
NIST Chemistry Reference: methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate(111112-50-6)
EPA Substance Registry System: methyl 5-methyl-6-methylene-2-oxobicyclo<3.2.1>octane-1-carboxylate(111112-50-6)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 111112-50-6(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 111112-50-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,1,1,1 and 2 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 111112-50:
(8*1)+(7*1)+(6*1)+(5*1)+(4*1)+(3*2)+(2*5)+(1*0)=46
46 % 10 = 6
So 111112-50-6 is a valid CAS Registry Number.

111112-50-6Upstream product

125801-31-2 2-Allyl-3-oxo-6-trimethylsilanylmethyl-hept-6-enoic acid methyl ester

111112-50-6Downstream Products

111112-50-6Relevant academic research and scientific papers

Manganese(III)-based oxidative free-radical tandem and triple cyclizations

Dombroski, Mark A.,Kates, Steven A.,Snider, Barry B.

, p. 2759 - 2767 (1990)

Tandem oxidative free-radical cyclization of 1a with Mn(OAc)3·2H2O and Cu(OAc)2·H2O in acetic acid at 25°C gives bicyclo[3.2.1]octane 7a in 86% yield. Oxidation of the β-ketoester gives the enol radical 2a which

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