1111166-00-7Relevant academic research and scientific papers
Gold- Vs. platinum-catalyzed polycyclizations by O-acyl migration. solvent-free reactions
Moreau, Xavier,Goddard, Jean-Philippe,Bernard, Matthieu,Lemiere, Gilles,Lopez-Romero, Juan Manuel,Mainetti, Emily,Marion, Nicolas,Mouries, Virginie,Thorimbert, Serge,Fensterbank, Louis,Malacria, Max
scheme or table, p. 43 - 48 (2009/04/08)
Polycyclic derivatives incorporating a cyclopropyl group have been efficiently synthesized from propargyl acetates using platinum(II), gold(I) and gold(III) catalysis. These reactions which are also viable for the preparation of medium-sized rings, proceed with a complete diastereocontrol and can also be run in neat conditions.
