3636-03-1Relevant articles and documents
Simple construction of bicyclo[4.3.0]nonane, bicyclo[3.3.0]octane, and related benzo derivatives by palladium-catalyzed cycloalkenylation
Toyota, Masahiro,Ilangovan, Andivelu,Okamoto, Rei,Masaki, Tomohito,Arakawa, Makoto,Ihara, Masataka
, p. 4293 - 4296 (2007/10/03)
(equation presented) Bicyclo[4.3.0]nonanes (hydrindanes) and bicyclo[3.3.0]octanes (octahydropentalenes) are easily synthesized by palladium-catalyzed cycloalkenylations. Additionally, benzo-fused bicyclo[3.3.0]octanes are prepared for the first time thro
A Facile Synthesis of Bicycloalkan-1-ols. Evidence for Organosamarium Intermediates in the Samarium(II) Iodide Promoted Intramolecular Barbier-Type Reaction
Molander, Gary A.,McKie, Jeffrey A.
, p. 4112 - 4120 (2007/10/02)
Samarium(II) iodide (SmI2) has been successfully employed as a reductive coupling agent for the intramolecular Barbier-type synthesis of bicycloalkan-1-ols.Thus, a variety of 3-(ω-iodoalkyl)cycloalkanones, upon treatment with SmI2 and a catalytic q
FREE RADICAL CARBOCYCLIC RING RECONSTRUCTION
Cekovic, Zivorad,Saicic, Radomir
, p. 5981 - 5984 (2007/10/02)
Alkenyl radical generated by β-fragmentation of tertiary cyclohexyloxy radical with carbocyclic ring opening, possessing a suitably located olefinic double bond, undergoes to the intramolecular 5-exo-trigonal cyclization and a new carbocyclic ring was for