111120-84-4

Upstream product

• 122358-32-1 Ethyl (E)-4-(formyloxy)-5-hydroxy-4-methyl-5-phenyl-2-pentenoate 
• 111120-83-3 Ethyl (+/-)-(E)-(4S^*,5S^*)-4,5-epoxy-4-methyl-5-phenyl-2-pentenoate 
• 343771-16-4 (+/-)-(2R^*,3S^*)-2,3-Epoxy-2-methyl-3-phenylpropanal 
• 129313-31-1 (+/-)-(2S^*,3S^*)-2,3-Epoxy-2-methyl-3-phenylpropan-1-ol 
• 1504-55-8 (E)-3-phenyl-2-methyl-2-propenol 

Downstream Products

• 122358-34-3 (4R^*,5S^*)-5-Hydroxy-4-methyl-5-phenylpentanoic acid 
• 91496-12-7 (+/-)-(5R^*,6S^*)-6-Phenyl-5-methyltetrahydropyran-2-one 
• 91496-12-7 (5S,6R)-5-Methyl-6-phenyl-tetrahydro-pyran-2-one 
• 118744-18-6 Ethyl (4R^*,5S^*)-5-hydroxy-4-methyl-5-phenylpentanoate 

Relevant academic research and scientific papers

Stereoselective Synthesis of (E)-5-Hydroxy-4-methyl-2-alkenoates by Palladium-Catalyzed Stereospecific Hydrogenolysis of (E)-4,5-Epoxy-4-methyl-2-alkenoates with Ammonium Formate

Palladium-catalyzed hydrogenolysis of (E)-4,5-epoxy-4-methyl-2-alkenoates with HCO2H-Et3N gave (E)-5-hydroxy-4-methyl-2-alkenoates in good yields with inversion of stereochemistry.

Palladium-Catalyzed Selective Hydrogenolysis of Alkenyloxiranes with Formic Acid. Stereoselectivity and Synthetic Utility

Selective hydrogenolysis of alkenyloxiranes to give homoallylic alcohols was carried out using formic acid in the presence of palladium-phosphine catalyst.The selectivity of the reaction depends on a nature and an amount of phosphine ligands.The reaction