111160-25-9

Upstream product

• 84736-38-9 (E/Z)-1-(benzyloxy)-1-(prop-1-enyloxy)propane 
• 138832-87-8 3R-methyl-4-(2R/S-tetrahydropyranyloxy)-1,2R/S-epoxybutane 
• 138832-88-9 4R-methyl-5-(2R/S-tetrahydropyranyloxy)-3R/S-pentanol 
• 129172-72-1 (R)-4-(2-tetrahydropyranyloxy)-3-methylbutene 
• 100-39-0 benzyl bromide 
• 138832-89-0 4R-methyl-5-(2R/S-tetrahydropyranyloxy)-3R/S-pentanol benzyl ether 

Downstream Products

• 138832-86-7 3R/S-benzyloxy-2R-methylpentanoic acid 3-pentyl ester 
• 108661-15-0 3R/S-benzyloxy-2R-methylpentanoic acid 
• 149-31-5 2-methyl-1,3-pentanediol 

Relevant academic research and scientific papers

SYNTHESIS OF ALL FOUR POSSIBLE ENANTIOMERS OF SITOPHILATE AGGREGATION PHEROMONE OF THE GRANARY WEEVIL

An efficient synthesis of the 3-pentyl ester of 2S-methyl-3R-hydroxypentanoic acid (sitophilate) and its 2S,3S-, 2R,3R-, and 2R,3S-isomers has been carried out starting from the available 2R-methyl-3-butenyl acetate as sole monochiral precursor.

Triisobutylaluminum-Assisted Reductive Rearrangement of Alkyl 1-Alkenyl Acetals: An Easy Synthesis of β-Alkoxy Alcohols

Alkyl 1-alkenyl acetals react with Al-i-Bu3 to give very good yields of β-alkoxy alcohols through a reductive rearrangement.The reaction is totally regioselective, but no stereocontrol occurs.