111182-16-2Relevant academic research and scientific papers
Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes
Cookson, James,Evans, Emma A.L.,Maher, John P.,Serpell, Christopher J.,Paul, Rowena L.,Cowley, Andrew R.,Drew, Michael G.B.,Beer, Paul D.
, p. 1195 - 1203 (2010)
The synthesis of a range of dinuclear Cu(II) dithiocarbamate (dtc)-based macrocycles and their characterisation are described. By carefully tuning the size of the aromatic spacer, cavities of different dimensions can be designed. The length and flexibility of the chosen spacer group dictates the intermetallic distance and hence the degree of communication between the two metal centres as evidenced by electrochemical and EPR experiments. This is illustrated by crystallographic evidence that show the macrocycles can host guests (such as CH2Cl2) or can fold and form unexpected Cu(I) dtc clusters.
Dinuclear zinc(II) dithiocarbamate macrocycles: Ditopic receptors for a variety of guest molecules
Wong, Wallace W. H.,Curiel, David,Cowley, Andrew R.,Beer, Paul D.
, p. 359 - 364 (2007/10/03)
The synthesis of a series of dinuclear zinc(II) dithiocarbamate (dtc) macrocyclic receptors containing aryl spacer groups of different sizes is reported. As evidenced from 1H NMR titration investigations, these receptors have the ability to bin
Synthesis of water-soluble diaza-1,2,5-thiadiazolo-cyclophanes
Hatta, Taizo,Kawano, Muneo,Imaizumi, Yuji,Tsuge, Akihiko,Moriguchi, Tetsuji,Maeda, Hironori,Tsuge, Otohiko
, p. 651 - 658 (2007/10/03)
The reaction of 3,4-bis(p-bromomethylphenyl)-1,2,5-thiadiazole (1) with bis(N-alkylaminomethyl)benzenes under high dilution conditions gave the diaza1,2,5-thiadiazolo[3.3.2]cyclophanes, while 1 reacted with xylylenediamines to give cupped diazathiadiazolo
