111198-03-9

Usage

Chemical structure

A benzotriazole derivative with a phenylthio group attached to the methylene bridge.

Corrosion inhibitor

Used to protect metals and alloys from corrosion in aqueous environments.

Stabilizer

Utilized in the production of plastics, coatings, and adhesives to prevent degradation from UV radiation.

Healthcare industry

Has potential applications as a medication for the treatment of certain diseases.

Safety concerns

Must be handled with caution due to potential health risks if not properly managed.

Upstream product

• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 108-98-5 thiophenol 
• 882-33-7 diphenyldisulfane 
• 100-68-5 methyl-phenyl-thioether 
• 65763-68-0 N-bromobenzotriazole 
• 95-14-7 1,2,3-Benzotriazole 
• 1373397-21-7 2-(trimethylsilyl)phenyl imidazol-1-sulfonate 
• 77422-70-9 azidomethyl phenyl sulphide 

Downstream Products

• 111198-16-4 2-Benzotriazol-1-yl-1,1-diphenyl-2-phenylsulfanyl-ethanol 
• 111198-18-6 1-((phenylsulfinyl)methyl)-1H-benzo[d][1,2,3]triazole 
• 111198-05-1 1-(phenylsulphonylmethyl)benzotriazole 
• 33192-00-6 2-(4-chlorophenyl)ethanonyl phenyl sulfide 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 189343-50-8 1-Benzotriazol-1-yl-1-phenylsulfanyl-nonadecan-2-one 
• 111198-17-5 (E)-2-Benzotriazol-1-yl-1-phenyl-2-phenylsulfanyl-vinylamine 
• 88064-00-0 1-[(1H-benzotriazol-1-yl)methyl]-1H-benzotriazole 
• 111198-12-0 1-(2-phenyl-1-phenylthioethyl)benzotriazole 
• 111198-14-2 1-benzotriazole 
• 111198-24-4 3-methyl-1-(phenylsulphonylmethy)benzotriazolium iodide 
• 111198-23-3 3-methyl-1-(phenylsulphinylmethy)benzotriazolium iodide 
• 111198-25-5 3-methyl-1-styrylbenzotriazolium iodide 
• 111198-21-1 1-benzotriazole 

Relevant academic research and scientific papers

Direct methyl C(sp3)-H azolation of thioanisoles: Via oxidative radical coupling

A method for metal-free, 1,3-dibromo-5,5-dimethylhydantoin mediated methyl C(sp3)-H bond azolation of thioanisoles has been developed, affording a facile route for the construction of nitrogen-functionalized thioanisoles, possibly via a nitrogen-centered radical process. This reaction represents an important addition to the limited number of existing methods for the methyl C(sp3)-H bond functionalization of thioanisoles, and may find practical application in the synthesis of nitrogen-alkylated azoles.

Design and application of new imidazolylsulfonate-based benzyne precursor: An efficient triflate alternative

Several o-(trimethylsilyl)aryl imidazolylsulfonates were synthesized in a simple process and successfully applied in cycloadditions involving benzyne intermediates. The precursor offers an efficient alternative for generating benzynes compared to widely used ortho TMS triflates under similar reaction conditions. With the utilization of this new precursor, the formation of potentially genotoxic trifluoromethanesulfonate side product is eliminated. The applicability of the new benzyne precursor was demonstrated in different types of cycloaddition reactions to prepare heterocyclic molecules.

Synthesis of α-benzotriazole sulfides promoted by samarium diiodide

1-(Benzotriazol-1-yl) unsymmetrical diorganyl sulfides were synthesized via replacement of chlorine atom in 1-(benzotriazol-1-yl)-1-chloromethane with thiolate anions promoted by SmI2.

The Chemistry of N-Substituted Benzotriazoles. Part 1. 1-(Chloromethyl)-benzotriazole

The N-chloromethyl group of 1-(chloromethyl)benzotriazole undergoes nucleophilic substitution by carbon, nitrogen, phosphorus, oxygen, and sulphur nucleophiles. α-Lithiation was achieved in high yield in 1-phenylthiomethyl-, 1-phenylsulphinylmethyl-, and 1-(phenylsulphonylmethyl)benzotriazoles and the lithio derivatives reacted with a variety of electrophiles.New benzotriazolium salts were prepared by quaternization of the N-3 nitrogen with methyl iodide.