1112-01-2Relevant academic research and scientific papers
19F nuclear magnetic resonance studies of halogenated propanes
Tanuma, T.,Ohnishi, K.,Okamoto, H.,Miyajima, T.,Morikawa, S.
, p. 259 - 284 (2007/10/02)
The relationship between 19F chemical shifts in halogenated propanes and their structures are elucidated using MNDO calculations to determine the population of rotamers.The pairs of atom gauche to a fluorine atom and van der Waals interaction between the two terminal substituents are responsible for the 19F chemical shifts.The differences among chemical shifts in diastereomers are also discussed in terms of the conformation of molecule.
Reaction of 1,1-Dichloro-2,2-difluoroethylene with Alkyl Grignard Reagents. Evidence for Radical Reaction Involving β-Hydrogen Atom Abstraction from Grignard Reagents. Implication Regarding the Mechanism of Reduction by Grignard Reagents
Okuhara, Kunio
, p. 244 - 252 (2007/10/02)
Reaction of CF2=CCl2 (1) with alkyl Grignard reagents (RMgX: R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, s-C4H9, i-C4H9, t-C4H9, n-C8H17, C6H5CH2) in ether afforded complex mixtures containing RCF2CCl2H (3), RCF=CCl2, CH3CH2OCH(CH3)CF2CCl2H, and CH3CH2OCH(CH3)
