111239-47-5

Basic information

• Product Name: 1,3-Butanedione, 2-methyl-1-phenyl-2-(2-propenyl)-, (R)-
• CAS NO: 111239-47-5
• Molecular Formula: C14H16O2
• Molecular Weight: 216.28
• Mol File: 111239-47-5.mol

Chemical Properties

• CAS DataBase Reference: 1,3-Butanedione, 2-methyl-1-phenyl-2-(2-propenyl)-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Butanedione, 2-methyl-1-phenyl-2-(2-propenyl)-, (R)-(111239-47-5)
• EPA Substance Registry System: 1,3-Butanedione, 2-methyl-1-phenyl-2-(2-propenyl)-, (R)-(111239-47-5)

Safety Data

• Hazardous Substances Data: 111239-47-5(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 6668-24-2 2-methyl-1-phenyl-1,3-butanedione 

Relevant articles and documents

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 5. Palladium-Catalyzed Asymmetric Allylation of Active Methine Compounds

Catalytic asymmetric allylation of sodium enolates of β-diketones with allyl acetate proceeded with high enantioselectivity in the presence of 0.5-1.0 mol percent of palladium complexes as catalysts bearing functionalized chiral ferrocenylphosphine ligand

Chiral phosphine ligands modified by crown ethers: An application to palladium-catalyzed asymmetric allylation of β-diketones

Chiral ferrocenylphosphine ligands modified by monoaza or diaza crown ethers of varying ring sizes and linker chain lengths (8a-e, 9) were synthesized. The reaction of the phosphine ligand modified by monoaza-18-crown-6 (8b) and the di-μ-chlorobis(T-allyl