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111269-40-0

1,2-Propanedione, 3,3,3-trifluoro-1-(4-methylphenyl)-, 1-(dimethylhydrazone) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 111269-40-0 Structure

  • Basic information

    1. Product Name: 1,2-Propanedione, 3,3,3-trifluoro-1-(4-methylphenyl)-, 1-(dimethylhydrazone)
    2. Synonyms:
    3. CAS NO:111269-40-0
    4. Molecular Formula: C12H13F3N2O
    5. Molecular Weight: 258.243
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 111269-40-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,2-Propanedione, 3,3,3-trifluoro-1-(4-methylphenyl)-, 1-(dimethylhydrazone)(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,2-Propanedione, 3,3,3-trifluoro-1-(4-methylphenyl)-, 1-(dimethylhydrazone)(111269-40-0)
    11. EPA Substance Registry System: 1,2-Propanedione, 3,3,3-trifluoro-1-(4-methylphenyl)-, 1-(dimethylhydrazone)(111269-40-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 111269-40-0(Hazardous Substances Data)

111269-40-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 111269-40-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,1,2,6 and 9 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 111269-40:
(8*1)+(7*1)+(6*1)+(5*2)+(4*6)+(3*9)+(2*4)+(1*0)=90
90 % 10 = 0
So 111269-40-0 is a valid CAS Registry Number.

111269-40-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(Dimethyl-hydrazono)-1,1,1-trifluoro-3-p-tolyl-propan-2-one

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:111269-40-0 SDS

111269-40-0Relevant articles and documents

A new facile synthesis of 5-aryl-4-trifluoroacetyl-6-trifluoromethyl-3,4-dihydro-2H-1,3,4-oxadia zines from arylaldehydes

Kamitori,Hojo,Masuda,Kawamura,Kawasaki,Ida

, p. 1183 - 1184 (1990)

By reaction with an excess of trifluoroacetic anhydride, title compounds 4 were synthesized from C-trifluoroacetylated hydrazones 1 which are readily obtainable by trifluoroacetylation of arylaldehyde dimethylhydrazones.

A convenient synthesis of 4,5-bis(trifluoromethyl)pyridazines

Kamitori, Yasuhiro,Hojo, Masaru,Yoshioka, Tatsuya

, p. 2221 - 2224 (2007/10/03)

Acid catalyzed selfcondensation of 3-hydrazono-1,1,1 trifluoroalkan-2-ones (2) prepared from 1,1,1-trifIuoroalkan-2,3-diones (1) and 100% hydrazine hydrate afforded 4,5-bis(trifluoromethyl)pyridazines (3) in satisfactory yields.

Electrophilic Substitution at Azomethine Carbon Atoms. Reaction of Aromatic Aldehyde Hydrazones with Trifluoroacetic Anhydride

Kamitori, Yasuhiro,Hojo, Masaru,Masuda, Ryoichi,Fujitani, Toshihiko,Ohara, Seiji,Yokoyama, Tetsuya

, p. 129 - 135 (2007/10/02)

Reaction of dimethylhydrazones of aromatic aldehydes with trifluoroacetic anhydride at room temperature affords high yields of products bearing trifluoroacetyl groups.These electrophilic substitution reactions generally occur on the azomethine carbon, although competitive N-acylation is observed in highly electron-rich systems.Use of diisopropylhydrazones suppressed this N-acylation completely, leading to high yields of C-acylated products.The trifluoroacetyl hydrazones can be cyclized thermally to imidazole and oxadiazine derivatives and can be converted into 1-trifluoromethyl 1,2-diketones by acid hydrolysis.

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