1112844-80-0

Basic information

• Product Name: 15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol
• Synonyms: 15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol
• CAS NO: 1112844-80-0
• Molecular Weight: 622.929
• Mol File: 1112844-80-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol(1112844-80-0)
• EPA Substance Registry System: 15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxa-bicyclo[3.2.1]octan-5-yl)pentadecan-1-ol(1112844-80-0)

Safety Data

• Hazardous Substances Data: 1112844-80-0(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 1112844-76-4 (1R,2R,5S,7R)-7-(5-(benzyloxy)pentyl)-5-(15-(tert-butyldimethylsilyloxy)pentadecyl)-6,8-dioxabicyclo[3.2.1]octan-2-ol 
• 1269799-12-3 (R)-1-(benzyloxy)-1-((4R,5R)-5-(5-(benzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-19-hydroxynonadecan-4-one 
• 1112844-78-6 (15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)(tert-butyl)dimethylsilane 

Downstream Products

• 1112844-45-7 C₄₁H₆₄O₇S 
• 1112844-81-1 tert-butyl 4-((15-((1R,2R,5S,7R)-2-(benzyloxy)-7-(5-(benzyloxy)pentyl)-6,8-dioxabicyclo[3.2.1]octan-5-yl)pentadecyloxy)methyl)-2,2-dimethyloxazolidine-3-carboxylate 

Relevant articles and documents

Metal-mediated alkynediol cycloisomerization: First and second generation formal total syntheses of didemniserinolipid B

A formal total synthesis of didemniserinolipid B was developed by employing a regioselective metal-mediated 6-endo-dig alkynol-cycloisomerization reaction. Two routes for the synthesis of key Burke's intermediate have been developed. Our initial approach

A formal synthesis of (+)-didemniserinolipid B employing a Pd-mediated 6-endo selective alkynediol cycloisomerization

Herein, we describe a concise assembly of central 6,8-dioxabicyclo[3,2,1]octane core of didemniserinolipid by employing a Pd-mediated alkynediol cycloisomerization and a formal total synthesis of didemniserinolipid B.