111302-04-6Relevant articles and documents
Electrophilic reactions of fluorocarbons under the action of aluminum chlorofluoride, a potent Lewis acid
Petrov, V. A.,Krespan, C. G.,Smart, B. E.
, p. 138 - 142 (2007/10/03)
A new Lewis acid - aluminum chlorofluoride - was demonstrated to be an effective catalyst for the isomerisation of fluoroolefins, polyfluorinated epoxides and cyclopropanes.At ambient temperature this catalyst converts perfluorobutadiene-1,3 into perfluorobutyne-2 and perfluoro(4-methylpentene-2) into perfluoro(2-methylpentene-2) in nearly quantitative yield.At 100 deg C, aluminum chlorofluoride causes the cleavage of perfluorinated tertiary amines. - Keywords: Electrophilic reactions; Fluorocarbons; Aluminum chlorofluoride; Lewis acid; NMR spectroscopy
FLUORINATION OF POLYHALOGENATED UNSATURATED COMPOUNDS WITH VANADIUM PENTAFLUORIDE
Bardin, V. V.,Avramenko, A. A.,Furin, G. G.,Krasilnikov, V. A.,Karelin, A. I.,et al.
, p. 385 - 400 (2007/10/02)
Vanadium pentafluoride reacts with polyfluorinated and polychlorinated olefins, alkadienes, cycloalkenes and cyclodienes in CFCl3 or without a solvent at -25 deg C to 100 deg C, forming products of addition of two fluorine atoms across the C=C bond.
INTRODUCTION OF A PENTAFLUOROPHENYL GROUP INTO PERFLUORINATED OLEFINS BY MEANS OF TRIMETHYLSILYLPENTAFLUOROBENZENE IN THE PRESENCE OF CESIUM FLUORIDE
Bardin, V. V.,Petrov, V. A.,Stennikova, I. V.,Furin, G. G.
, p. 46 - 49 (2007/10/02)
Trimethylsilylpentafluorobenzene reacts with terminal and internal perfluorinated olefins in the presence of cesium fluoride, forming perfluorinated phenylalkenes.
AN UNUSUAL TRANSFORMATION OF PERFLUORINATED 1- AND 3-PHENYLPROPENES TO POLYFLUOROCHLOROINDANES BY THE ACTION OF AlCl3
Platonov, V. E.,Dvornikova, K. V.
, p. 2617 - 2619 (2007/10/02)
The reaction of perfluorinated 1- and 3-phenylpropenes with AlCl3 gives polyfluorochloroindanes as the result of an intramolecular cyclization, apparently by an electrophilic pathway.
