111462-91-0Relevant academic research and scientific papers
Monoalkylaminomethylation d'organometalliques a l'aide de N-alkyl N-trimethylsilyl alkoxymethylamines
Courtois, G.,Miginiac, L.
, p. 127 - 142 (1988)
The simple or functional N-alkyl-N-trimethylsilylalkoxymethylamines are very convenient new reagents for the route to unsymmetrical secondary functional amines from organometallic compounds (M=Al, Mg, Zn) prepared from α-unsaturated halides, functional terminal alkynes or α-bromoesters (or amides).
Aminomethylation secondaire ou primaire d'organoaluminiques α-insatures a l'aide de gem-aminoethers N-trimethylsilyles: synthese d'amines secondaires ou primaires, β-ethyleniques, β-acetyleniques ou α-alleniques
Courtois, G.,Mesnard, D.,Dugue, B.,Miginiac, L.
, p. 93 - 98 (2007/10/02)
Organoaluminium compounds prepared from allylic or propargylic halides react easily with N-trimethylsilyl or N,N-bis(trimethylsilyl) gem-aminoethers to afford in a one-pot reaction unsaturated secondary (with tertiary alkyl group) or primary amines.
