Monoalkylaminomethylation d'organometalliques a l'aide de N-alkyl N-trimethylsilyl alkoxymethylamines

Article abstract of DOI:10.1016/0022-328X(88)80069-X

The simple or functional N-alkyl-N-trimethylsilylalkoxymethylamines are very convenient new reagents for the route to unsymmetrical secondary functional amines from organometallic compounds (M=Al, Mg, Zn) prepared from α-unsaturated halides, functional terminal alkynes or α-bromoesters (or amides).