111468-63-4Relevant academic research and scientific papers
Cross-Coupling of Organosilanes with Organic Halides Mediated by Palladium Catalyst and Tris(diethylamino)sulfonium Difluorotrimethylsilicate
Hatanaka, Yasuo,Hiyama, Tamejiro
, p. 918 - 920 (1988)
In the presence of tris(diethylamino)sulfonium difluorotrimethylsilicate (TASF) and allylpalladium chloride dimer as a catalyst, organosilicon compounds like vinyl-, ethynyl-, and allylsilanes react with such organic halides as aryl, vinyl, and allyl halides to give the corresponding coupled products in synthetically useful yields in a stereospecific and chemoselective manner.
